Condensation Reaction of Ferrocene with Carbonyl Compounds
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منابع مشابه
Condensation Reactions of 2-Aminobenzohydrazide with Various Carbonyl Compounds
Technical iodine was found to catalyze the condensation between 2-aminobenzohydrazide (1) and some aldehydes and ketones in absolute ethanol under mild conditions to afford hydrazone and quinazoline derivatives, respectively. Condensation of 1 with terephthalaldehyde (2) in 1 : 1 molar ratios afforded the hydrazone 3, while hydrazone 4 was formed on using a double molar ratio of 1. On the other...
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The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoesters were also synthesized by the condensation with formanilides.
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Monoand poly-nuclear metal carbonyls, and substituted analogues, have been analysed in the presence of N3 − ions by negative-ion electrospray mass spectrometry. Most complexes yield the appropriate isocyanate-containing anions by conversion of a CO ligand to an NCO one with elimination of N2. In some cases [M+N3] − ions are observed; for species such as H2Os3(CO)10 or Ru5C(CO)15 these arise fro...
متن کاملSynthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR].
The reaction between a transition metal carbonyl compound, L(n)MCO, and Li[Me(3)SiNR] yields the corresponding isocyanide derivative, L(n)MCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1968
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.41.1891